Publications

The following is a list of the reaction kinetic group's thesis and key publications in peer-re­viewed journ­als.

Thesis related to the laser photolysis photoionization mass spectrometer (LP-PIMS) apparatus:

Publications related to the laser photolysis photoionization mass spectrometer (LP-PIMS) apparatus:

  1. T. T. Pekkanen, R. S. Timonen, E. A. Ramu, G. Lendvay, A. J. Eskola: The Temperature and Pressure Dependence of the Reaction Between Ethyl Radical and Molecular Oxygen: Experiments and Master Equation Simulations. Journal of Physical Chemistry A, 2022, Accepted manuscript, doi:10.1021/acs.jpca.2c07780
  2. Timo T. Pekkanen, György Lendvay, Malte Döntgen, Raimo S. Timonen, Arkke J. Eskola: An Experimental and Computational Investigation of the Reaction Between Pent-1-en-3-yl Radicals and Oxygen Molecules Under Autoignition Conditions. PROCEEDINGS OF THE COMBUSTION INSTITUTE, Accepted, doi:10.1016/j.proci.2022.07.176
  3. Arkke J. Eskola, Timo T. Pekkanen, György Lendvay, and Raimo S. Timonen: An experimental and theoretical kinetic study of t-butyl radical reaction with molecular oxygen. PROCEEDINGS OF THE COMBUSTION INSTITUTE, Accepted, doi:10.1016/j.proci.2022.06.003
  4. Timo T. Pekkanen, Laszlo Valkai, Satya P. Joshi, György Lendvay, Petri Heinonen, Raimo S. Timonen, and Arkke J. Eskola: An Experimental and Computational Study of the Reaction between Pent-3-en-2-yl Radicals and Oxygen Molecules: Switching from Pure Stabilisation to Pure Decomposition with Increasing Temperature. Faraday Discuss., 2022, 238, 619 – 644, doi:10.1039/D2FD00031H
  5. Satya P. Joshi, Timo T. Pekkanen, Prasenjit Seal, Raimo S. Timonen, Arkke J. Eskola: An Experimental and Master-Equation Modeling Study of the Kinetics of the Reaction between Resonance-Stabilized (CH3)2CCHCH2 Radical and Molecular Oxygen. Phys. Chem. Chem. Phys., 2021, 23: 20419–20433, doi:10.1039/D1CP02210E
  6. Timo T. Pekkanen, Raimo S. Timonen, Struan H. Robertson, György Lendvay, Satya P. Joshi, Timo T. Reijonen, and Arkke J. Eskola: An Experimental and Computational Study of the Reaction Between 2-Methylallyl Radicals and Oxygen Molecules: Optimizing Master Equation Parameters with Trace Fitting. Phys. Chem. Chem. Phys., 2022, 24, 4729–4742
  7. Arkke J. Eskola, Timo T. Reijonen, Timo T. Pekkanen, Petri Heinonen, Satya P. Joshi, Raimo S. Timonen: First Direct Kinetic Measurement of i-C4H5 (CH2CHCCH2) + O2 Reaction: Toward Quantitative Understanding of Aromatic Ring Formation Chemistry. PROCEEDINGS OF THE COMBUSTION INSTITUTE, 2021, 38(1), 813–821
  8. Timo T. Pekkanen, Satya P. Joshi, György Lendvay, Raimo S. Timonen, Arkke J. Eskola: Kinetics and thermochemistry of the reaction of 1-methylpropargyl radicals with oxygen molecules: experiments and computations. PROCEEDINGS OF THE COMBUSTION INSTITUTE, 2021, 38(1), 843–852
  9. Satya Prakash Joshi, Prasenjit Seal, Timo Theodor Pekkanen, Raimo Sakari Timonen, Arkke Johannes Eskola: Direct Kinetic Measurements and Master Equation Modelling of the Unimolecular Decomposition of Resonantly-Stabilized CH2CHCHC(O)OCH3 Radical and an Upper Limit Determination for CH2CHCHC(O)OCH3 + O2 Reaction. Z. Phys. Chem., 2020, 234, 7-9, 1251–1268
  10. S. P. Joshi, T. T Pekkanen, R. S Timonen, A. J. Eskola: Effect of Methyl Group Substitution on the Kinetics of Vinyl Radical + O2 Reaction. Journal of Physical Chemistry A, 2019, 123 (49), 10514–10519
  11. M. Döntgen, T. T. Pekkanen, S. P. Joshi, R. S. Timonen, A. J. Eskola: Oxidation Kinetics and Thermodynamics of Resonance-Stabilized Radicals: The Pent-1-en-3-yl + O2 Reaction. Journal of Physical Chemistry A, 2019, 123 (37), 7897−7910
  12. S. P. Joshi, T. T. Pekkanen, R. S. Timonen, G. Lendvay, A. J. Eskola: Kinetics of the Methyl-Vinyl Radical + O2 Reactions Associated with Propene Oxidation. Journal of Physical Chemistry A, 2019, 123 (5), 999–1006
  13. A. J. Eskola, T. T. Pekkanen, S. P. Joshi, R. S. Timonen, S. J. Klippenstein: Kinetics of 1-butyl and 2-butyl radical reactions with molecular oxygen: Experiment and theory. PROCEEDINGS OF THE COMBUSTION INSTITUTE, 2019, 37 (1), 291 – 298
  14. T. T. Pekkanen, R. S. Timonen, G. Lendvay, M. P. Rissanen, A. J. Eskola: Kinetics and thermochemistry of the reaction of 3-methylpropargyl radical with molecular oxygen. PROCEEDINGS OF THE COMBUSTION INSTITUTE, 2019, 37 (1), 299-306
  15. T. T. Pekkanen, S. L. Arppe, A. J. Eskola, M. P. Rissanen, R. S. Timonen: An Experimental Study of the Kinetics of the Reactions of Isopropyl, sec-Butyl, and tert-Butyl Radicals with Molecular Chlorine at Low Pressures (0.5–7.0 Torr) in the Temperature Range 190–480 K. International Journal of Chemical Kinetics, 2016, 48 (12), 796–805
  16. Ravi X. Fernandes, Klaus Luther, Gerd Marowsky, Matti P. Rissanen, Raimo Timonen, and Jürgen Troe: Experimental and Modeling Study of the Temperature and Pressure Dependence of the Reaction C2H5 + O2 (+M) -> C2H5O2 (+M). JOURNAL OF PHYSICAL CHEMISTRY A, 2015, 119 (28), ‏ 7263-7269
  17. Matti P. Rissanen, Marvin Ihlenborg, Timo T. Pekkanen, and Raimo S. Timonen: Kinetics of Several Oxygen-Containing Carbon-Centered Free Radical Reactions with Nitric Oxide. JOURNAL OF PHYSICAL CHEMISTRY A, 2015, 119 (28), ‏ 7734-7741
  18. M. P. Rissanen, A. J. Eskola, T. L. Nguyen, J. R. Barker, J. Liu, J. Liu, E. Halme, and R. S. Timonen: CH2NH2 + O2 and CH3CHNH2 + O2 Reaction Kinetics: Photoionization Mass Spectrometry Experiments and Master Equation Calculations. Journal of Physical Chemistry A, 2014, 118 (12), 2176–2186
  19. Matti P. Rissanen, Suula L. Arppe, Raimo S. Timonen: Kinetics of Several Oxygenated Carbon-Centered Free Radical Reactions with NO2. JOURNAL OF PHYSICAL CHEMISTRY A, 2013, 117 (19), 3902-3908
  20. Matti P. Rissanen, Damien Amedro, Lev Krasnoperov, Paul Marshall, and Raimo S. Timonen: Gas Phase Kinetics and Equilibrium of Allyl Radical Reactions with NO and NO2. JOURNAL OF PHYSICAL CHEMISTRY A, 2013, 117 (5), 793-805
  21. Matti P.Rissanen, Khushhal Popli, and Raimo S. Timonen: Kinetics of resonance stabilized CH3CCCH2 radical reactions with NO and NO2. CHEMICAL PHYSICS LETTERS, 2012, 543, 28-33
  22. Matti P. Rissanen, Arkke J. Eskola, Raimo S. Timonen: Kinetics of the brominated alkyl radical (CHBr2, CH3CHBr) reactions with NO2 in the temperature range 250 ‒ 480 K. International Journal of Chemical Kinetics, 2012, 44(12), 767‒777
  23. Matti P. Rissanen, Damien Amedro, Arkke J. Eskola, Theo Kurten, Raimo S. Timonen: Kinetic (T = 201 ‒ 298 K) and Equilibrium (T = 320 ‒ 420 K) Measurements of the C3H5 + O2 ↔ C3H5O2 Reaction. Journal of Physical Chemistry A, 2012, 116(16), 3969–3978
  24. Matti P. Rissanen, Suula L. Arppe, Arkke J. Eskola, Matti M. Tammi, Raimo S. Timonen: Kinetics of the R + NO2 reactions (R= i-C3H7, n-C3H7, s-C4H9 and t-C4H9) in the temperature range 201 – 489 K. Journal of Physical Chemistry A, 2010, 114(14), 4811 – 4817
  25. Matti P. Rissanen, Arkke J. Eskola, Raimo S. Timonen: Kinetics of the reactions of CH2Cl, CH3CHCl and CH3CCl2 radicals with Cl2 in the temperature range 191 – 363 K. Journal of Physical Chemistry A, 2010, 114(14), 4805 – 4810
  26. Matti P. Rissanen, Arkke J. Eskola, Elena Savina, Raimo S. Timonen: Kinetics of the Reactions of CH3CH2, CH3CHCl, and CH3CCl2 Radicals with NO2 in the Temperature Range 221– 363 K. Journal of Physical Chemistry A, 2009, 113(9), 1753-1759
  27. Arkke J. Eskola, Raimo S. Timonen, Paul Marshall, Evgeni N. Chesnokov, Lev N. Krasnoperov: Rate Constants and Hydrogen Isotope Substitution Effects in the CH3 + HCl and CH3 + Cl2 Reactions. Journal of Physical Chemistry A, 2008, 112(32), 7391-7401
  28. Arkke J. Eskola, Iwona Golonka, Matti P. Rissanen, Raimo S. Timonen: Kinetics of the CCl2 +Br2 and CCl2 +NO2 reactions in the temperature range 266 − 365K and reactivity of the CCl2 biradical. Chemical Physics Letters, 2008, 460(4-6), 401-405
  29. Jorma A. Seetula, Arkke J. Eskola: Kinetics of the R + HBr ↔ RH + Br (CH3CHBr, CHBr2 or CDBr2) equilibrium. Thermochemistry of the CH3CHBr and CHBr2 radicals. Chemical Physics, 2008, 351, 1-3
  30. Arkke J. Eskola, Vladimir A. Lozovsky, Raimo S. Timonen: Kinetics of the Reactions of C2H5, n-C3H7, and n-C4H9 Radicals with Cl2 at the Temperature Range 190 – 360 K. Int. J. Chem. Kinet., 2007, 39, 614-619
  31. Arkke J. Eskola, Jorma J. Seetula, Raimo S. Timonen: Kinetics of the of CH3 + HCl/DCl → CH4/CH3D + Cl and CD3 + HCl/DCl → CD3H/CD4 + Cl reactions: An experimental H atom tunneling investigation. Chemical Physics, 2006, 331, 26-34
  32. Arkke J. Eskola, Dorota Wojcik-Pastuszka, Emil Ratajczak, Raimo S. Timonen: Kinetics of the reactions of CH2I, CH2Br, and CHBrCl radicals with NO2 in the temperature range 220 − 360 K. J. Phys. Chem. A, 2006, 110, 12177-12183
  33. Arkke J. Eskola, Dorota Wojcik-Pastuszka, Emil Ratajczak, Raimo S. Timonen: Kinetics of the reactions of CH2Br and CH2I radicals with molecular oxygen at atmospheric temperatures. Phys. Chem. Chem. Phys., 2006, 8, 1416-1424
  34. Arkke J. Eskola, Wolf D. Geppert, Matti P. Rissanen, Raimo S. Timonen, Lauri Halonen: Kinetics of the reactions of chlorinated methyl radicals (CH2Cl, CHCl2, and CCl3) with NO2 in the temperature range 220 − 360 K. J. Phys. Chem. A, 2005, 109, 5376-5381
  35. W. D. Geppert, A. J. Eskola, R. S. Timonen, L. Halonen: Kinetics of the reactions of vinyl (C2H3) and propargyl (C3H3) radicals with NO2 in the temperature range 220 – 340 K. J. Phys. Chem. A, 2004, 108, 4232-4238
  36. A. J. Eskola, R. S. Timonen: Kinetics of the reactions of vinyl radicals with molecular oxygen and chlorine at temperatures 200 – 362 K. Phys. Chem. Chem. Phys., 2003, 5, 2557-2561

 

Thesis related to the time-resolved, broadband, cavity-enhanced absorption spectrometer (TR-BB-CEAS) apparatus:

Publications related to the time-resolved, broadband, cavity-enhanced absorption spectrometer (TR-BB-CEAS) apparatus:

  1. Lauri Franzon, Jari Peltola, Rashid Valiev, Niko Vuorio, Theo Kurtén, and Arkke Eskola: An Experimental and Master Equation Investigation of Kinetics of the CH2OO + RCN Reactions (R = H, CH3, C2H5) and Their Atmospheric Relevance.  J. Phys. Chem. A, 2023, Accepted manuscript, doi:10.1021/acs.jpca.2c07073

  2. Jari Peltola, Prasenjit Seal, Niko Vuorio, Petri Heinonen, and Arkke Eskola: Solving the discrepancy between the direct and relative-rate determinations of unimolecular reaction kinetics of dimethyl-substituted Criegee intermediate (CH3)2COO using a new photolytic precursor. Phys. Chem. Chem. Phys., 2022, 24, 5211–5219

  3. Jari Peltola, Prasenjit Seal, Anni Inkilä and Arkke Eskola: Time-resolved, broadband UV-absorption spectrometry measurements of Criegee intermediate kinetics using a new photolytic precursor: Unimolecular decomposition of CH2OO and its reaction with formic acid. Phys. Chem. Chem. Phys., 2020, 22: 11797 – 11808

 

A complete list of Dr. Eskolas's publications can be found here.