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University of Helsinki VERIFIN - Finnish Institute for Verification of the Chemical Weapons Convention
 
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VERIFIN:
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Address:
A. I. Virtasen aukio 1 (P.O. Box 55)
Department of Chemistry
FI-00014 University of Helsinki
tel. +358 9 191 50443
fax +358 9 191 50437
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firstname.lastname@helsinki.fi

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Scientific Papers

Development and validation of efficient stable isotope dilution LC-HESI-MS/MS method for the verification of ?-lyase metabolites in human urine after sulfur mustard exposure
Mia Halme, Maaret Karjalainen, Harri Kiljunen and Paula Vanninen
J. Chromatogr. B (2011) 879, 908-914.

Capsaicinoids, chloropicrin and sulfur mustard: Possibilities for exposure biomarkers
Maija Pesonen, Kirsi Vähäkangas, Mia Halme, Paula Vanninen, Heikki Seulanto, Matti Hemmilä, Markku Pasanen and Tapio Kuitunen
Frontiers in Predictive Toxicity (2010) 1, 140.

Structural characterization of chemical warfare agent degradation products in decontamination solutions with proton band-selective 1H-31P NMR spectroscopy
Harri Koskela, Ullastiina Hakala and Paula Vanninen
Anal. Chem. (2010) 82, 5331-5340.

Tetradecyl(trihexyl)phosphonium chloride ionic liquid single-drop microextraction for electrothermal atomic absorption spectrometric determination of lead in water samples
Estefanía M. Martinisa, Paula Bertóna, Jorgelina C. Altamiranoa, Ullastiina Hakala and Rodolfo G. Wuillouda
Talanta (2010) 80, 2034-2040.

Use of NMR techniques for toxic organophosphorus compound profiling
Harri Koskela
J. Chromat. B (2010) 878, 1365-1381.

Quantitative two-dimensional HSQC experiment for high magnetic field NMR spectrometers
Harri Koskela, Outi Heikkilä, Ilkka Kilpeläinen and Sami Heikkinen
J. Magn. Reson. (2010) 202, 24-33.

Environmental Hazards of Sea-Dumped Chemical Weapons - Does the post-WWII burial at sea of chemical weapons still pose a human and environmental risk?
Hans Sanderson, Patrik Fauser, Marianne Thomsen, Paula Vanninen, Martin Soderstrom, Yuri Savin, Ildus Khalikov, Anu Hirvonen, Susa Niiranen, Tine Missiaen, Alexander Gress, Pavel Borodin, Nadezda Medvedeva, Yulia Polyak, Vadim Paka, Victor Zhurbas and Pascal Feller
Environ. Sci. Technol. (2010) 44, 4389-4394.

Evaluation of a chemical munition dumpsite in the Baltic Sea based on geophysical and chemical investigations
Tine Missiaen, Martin Söderström, Irina Popescu and Paula Vanninen
Sci. Total Environ. (2010) 408, 3536-3553.

Sample Preparation for Analysis of Chemicals Related to the Chemical Weapons Convention in an Off-site Laboratory
Marja-Leena Kuitunen
Encyclopedia of Analytical Chemistry: Chemical Weapons Chemicals Analysis, ed. R.A. Meyers, John Wiley, Chichester 15 December 2010, DOI: 10.1002/9780470027318.a0410.pub2.

Nuclear magnetic resonance spectroscopy in analysis of chemicals related to the Chemical Weapons Convention
Markku Mesilaakso, Urs Meier and Harri Koskela
Encyclopedia of Analytical Chemistry: Chemical Weapons Chemicals Analysis (2009) doi: 10.1002/9780470027318.a0409.pub2.

Atomic structures of two novel immunoglobulin-like domain pairs in the actin cross-linking protein filamin
Outi K. Heikkinen, Salla Ruskamo, Peter V. Konarev, Dmitri I. Svergun, Tatu Iivanainen, Sami M. Heikkinen, Perttu Permi, Harri Koskela, Ilkka Kilpeläinen, and Jari Ylänne
J. Biol. Chem. (2009) 284, 25450-25458.

Quantitative 2D NMR studies
Harri Koskela
Ann. Rep. NMR Spectrosc. (2009) 66, 1-31.

Solution structure of the first immunoglobulin domain of human myotilin
Outi Heikkinen, Perttu Permi, Harri Koskela, Olli Carpén, Jari Ylänne and Ilkka Kilpeläinen
J. Biomol. NMR (2009) 44, 107-112.

1H, 13C and 15N resonance assignments of the human filamin A tandem immunoglobulin-like domains 16-17 and 18-19
Outi Heikkinen, Perttu Permi, Harri Koskela, Jari Ylänne and Ilkka Kilpeläinen
Biomol. NMR Assign. (2009) 3, 53-56.

On-Flow Pulsed Field Gradient Heteronuclear Correlation Spectrometry in Off-Line LC-SPE-NMR Analysis of Chemicals Related to the Chemical Weapons Convention
Harri Koskela, Mia Ervasti, Heikki Björk and Paula Vanninen
Anal. Chem. (2009) 81, 1262-1269.

Solution structure of the parvulin-type PPIase domain of Staphylococcus aureus PrsA - Implications for the catalytic mechanism of parvulins
Outi Heikkinen, Raili Seppala, Helena Tossavainen, Sami Heikkinen, Harri Koskela, Perttu Permi and Ilkka Kilpeläinen
BMC Struct. Biol. (2009) 9:17, doi:10.1186/1472-6807-9-17.

Application of a Microcoil Probe Head in NMR Analysis of Chemicals Related to the Chemical Weapons Convention
Harri Koskela and Paula Vanninen
Anal. Chem. (2008) 80, 5556-5564.

NMR properties of conjugated linoleic acid (CLA) methyl ester hydroperoxides
Taina I. Pajunen, Harri Koskela, Tapio Hase, and Anu Hopia
Chem. Phys. Lipids (2008) 154, 105-144.

Determination of Trace Amounts of Chemical Warfare Agent Degradation Products in Decontamination Solutions with NMR Spectroscopy
Harri Koskela, Marja-Leena Rapinoja, Marja-Leena Kuitunen, and Paula Vanninen
Anal. Chem. (2007) 79, 9098-9106 .

Continuous H/D exchange of aromatic hydrocarbons using near-critical deuterium oxide
Boris Kerler, Jaroslav Pól, Kari Hartonen, Martin T. Söderström, Harri T. Koskela and Marja-Liisa Riekkola
J. Supercritical Fluids (2007) 39, 381-388.

Hafnium Bis(phenoxyimino) Dibenzyl Complexes and Their Activation toward Olefin Polymerization
Kirill V. Axenov, Martti Klinga, Olli Lehtonen, Harri T. Koskela, Markku Leskelä, and Timo Repo
Organometallics (2007) 26, 1444-1460.

Rapid and Accurate Processing Method for Amide Proton Exchange Rate Measurement in Proteins
Harri Koskela, Outi Heikkinen, Ilkka Kilpeläinen, and Sami Heikkinen
J. Biomol. NMR (2007)37, 313-320 .

Screening and Identification of Organophosphorus Compounds Related to the Chemical Weapons Convention with 1D and 2D NMR Spectroscopy
Harri Koskela, Nicoleta Grigoriu, and Paula Vanninen
Anal. Chem.(2006) 78, 3715-3722.

Insertion of Noble Gas Atoms into Cyanoacetylene: Ab Initio and Matrix Isolation Study
Leonid Khriachtchev, Antti Lignell, Hanna Tanskanen, Jan Lundell, Harri Kiljunen and Markku Räsänen
J.Phys.Chem A (2006), 110(42), 11876-11885.

Some Aspects of Quantitative 2D NMR.
Koskela, H.; Kilpeläinen I.; Heikkinen S.
Journal of Magnetic Resonance (2005), 174, 237-244.

Analysis Strategy for Analysis of Chemicals Related to the Chemical Weapons Convention in an Off-site Laboratory
Mesilaakso, M.
Chemical Weapons Convention Chemicals Analysis; Sample Collection, Preparation and Analytical Methods, M. Mesilaakso (Ed.), Wiley & Sons (2005), 151-162.

Sample Preparation for Analysis of Chemicals Related to the Chemical Weapons Convention in an Off-site Laboratory
Kuitunen, M-L.
Chemical Weapons Convention Chemicals Analysis; Sample Collection, Preparation and Analytical Methods, M. Mesilaakso (Ed.), Wiley & Sons (2005), 163-184.

Gas Chromatography in Screening of Chemicals Related to the Chemical Weapons Convention
Kostiainen, O.
Chemical Weapons Convention Chemicals Analysis; Sample Collection, Preparation and Analytical Methods, M. Mesilaakso (Ed.), Wiley & Sons (2005), 185-249.

Nuclear Magnetic Resonance Spectroscopy in Analysis of Chemicals Related to the Chemical Weapons Convention in an Off-site Laboratory
Mesilaakso, M.; Niederhauser, A.
Chemical Weapons Convention Chemicals Analysis; Sample Collection, Preparation and Analytical Methods, M. Mesilaakso (Ed.), Wiley & Sons (2005), 321-352.

Fourier Transform Infrared Spectroscopy in Analysis of Chemicals Related to the Chemical Weapons Convention in an Off-site Laboratory
Söderström, M. T.
Chemical Weapons Convention Chemicals Analysis; Sample Collection, Preparation and Analytical Methods, M. Mesilaakso (Ed.), Wiley & Sons (2005), 353-386.

CAGEBIRD: Improving the GBIRD Filter with a CPMG Sequence.
Koskela, H.; Kilpeläinen I.; Heikkinen S.
Journal of Magnetic Resonance (2004), 170, 121-126.

Preparation of fluorine-18-labeled fluoromisonidazole using two different synthesis methods.
Kämäräinen, E.-L.; Kyllönen, T.; Nihtilä, O.; Björk, H.; Solin, O.
Journal of Labeled Compounds & Radiopharmaceuticals (2004), 47(1), 37-45.

Fluorine-free organoxenon chemistry: HXeCCH, HXeCC, and HXeCCXeH
Khriachtchev L.; Tanskanen H.; Lundell J.; Pettersson M.; Kiljunen H.; Räsänen M.
Journal of the American Chemical Society (2003), 125(16), 4696-7.

A gate to organokrypton chemistry: HKrCCH.
Khriachtchev L.; Tanskanen H.; Cohen A.; Gerber R B.; Lundell Jan; Pettersson M.; Kiljunen H.; Räsanen M.
Journal of the American Chemical Society (2003), 125(23), 6876-7.

Chemical compounds formed from diacetylene and rare-gas atoms: HKrC4H and HXeC4H.
Tanskanen H.; Khriachtchev L.; Lundell J.; Kiljunen H.; Rasanen M.
Journal of the American Chemical Society (2003), 125(52), 16361-6.

Fluorine-Free Organoxenon Chemistry: HXeCCH, HXeCC, and HXeCCXeH.
Khriachtchev, L.; Tanskanen, H.; Lundell, J.; Pettersson, M.; Kiljunen, H.; Räsänen, M.
Journal of the American Chemical Society (2003), 125(16), 4696-4697.

The incorporation of 3,4-dichloroaniline, a pesticide metabolite, into dehydrogenation polymers of coniferyl alcohol (DHPs). Part 2. Identification of a dimeric adduct.
Brunow, G.; Raiskila, S.; Björk, H.
Holzforschung (2002), 56(1), 73-75.

Regioselectivity of Methylation of O-Demethylangolensin [1-(2,4-Dihydroxyphenyl)-2-(4-hydroxyphenyl)propan-1-one]. An Expedient Synthesis of Angolensin.
Wähälä, K.; Jokela, T.; Salakka, A.; Kaltia, S.; Mesilaakso, M.
J. Chem. Soc., Perkin Trans. 1 (2001), 642-644.

The Identification of Dilignols from Dehydrogenation Mixtures of Coniferyl Alcohol and Apocynol [4-(1-Hydroxyethyl)-2-methoxyphenol] by LC-ES-MS/MS.
Syrjänen, K.; Sipilä, J.; Björk, H.; Brunow, G.
Journal of Agricultural and Food Chemistry (2000), 48(11).

Two-dimensional TLC separation and mass spectrometric identification of anthraquinones isolated from the fungus Dermocybe sanguinea.
Räisänen, R; Björk, H; Hynninen, P, H.
Zeitschrift fuer Naturforschung, C: Journal of Biosciences (2000), 55(3/4), 195-202.

Analysis of 1H and 13C{1H} NMR Spectral Parameters and Geometries of Three Isomeric Diphenylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydrides.
Kokko, M.; Mesilaakso, M.; Pajunen, A.
Spectroscopy Letters 33 (2000), 717-734.

Chrystallographic and NMR Analyses of 9-Phenylthiohenanthrene and 9-t-Butylthiophenanthrene.
Sipilä, K.; Kansikas, J.; Mesilaakso, M.
J. Chem. Soc., Perkin Trans. 2 (1999), 1841-1845.

Analysis of NMR-spectral Parameters and Molecular Dynamics Study of 3-Quinuclidinol and 3-Quinuclidinyl Benzilate.
Heikkinen, S.; Mesilaakso, M.; Rahkamaa, E.
Magn. Reson. Chem. (1998), 36, 627-634.

Analysis of volatile organic compounds in air using retention indices together with a simple thermal desorption and cold trap method.
Kivi-Etelätalo, E; Kostiainen, O; Kokko, M.
Journal of Chromatography, A (1997), 787(1 + 2), 205-214.

The Synthesis, Structure and Anticancer Activity of cis- and trans-4',7-Dihydroxyisoflavan-4-ols.
Wähälä, K.; Koskimies, J. K.; Mesilaakso, M.; Salakka, A. K.; Leino, T. K.; Adlercreutz, H.
J. Org. Chem. (1997), 62, 7690-7693.

Fragmentation of protonated O,O-diethyl O-aryl phosphorothionates in tandem mass spectral analysis.
Kuivalainen, T; Kostiainen, R; Uggla, R; Sundberg, M; Björk, H.
Journal of the American Society for Mass Spectrometry (1996), 7(2), 189-97.

Isolation and Structure Elucidation of the Main Photodecomposition Product of Trichloromethiazide.
Ulvi, V.; Mesilaakso, M.; Matikainen, J.
Pharmazie (1996), 51, 774-775.

Fragmentation of protonated O,O-dimethyl O-aryl phosphorothionates in tandem mass spectral analysis.
Kuivalainen, T.; Kostiainen, R.; Björk, H.; Uggla, R.; Sundberg, M. R.
Journal of the American Society for Mass Spectrometry (1995), 6(6), 488-97.

Structure Elucidation of 6-Chloro-2-methyl-4(1H)-quinazolinone, a Photodecomposition Product of Midazolam.
Andersin, R.; Mesilaakso, M.
J. Pharm. Biomed. Anal. (1995), 13, 667-670.


Doctoral theses

Some aspects of polarisation transfer in NMR spectroscopy (PhD dissertation)
Harri Koskela
Acta Universitatis Ouluensis, A442, 2005

Verification by NMR Spectroscopy of Chemicals Related to the Chemical Weapons Convention
Markku Mesilaakso
University of Oulu, Department of Chemistry, 1998

Development of a retention Index Monitoring Method for Reversed-Phase High-Performance Liquid Chromatography of Non-Phosphorus Chemical Warfare Agents
Pirjo Kuronen
University of Helsinki, Department of Chemistry, Organic laboratory, 1990

The Characterization and Analysis of Trichothecenes by Chemical Ionization and Tandem Mass Spectrometry
Risto Kostiainen
University of Helsinki, Department of Chemistry, Analytical laboratory, 1989

The Effects of Substituents on Certain Properties of Organic Phosphates and Phosphonates
Antti Manninen
University of Helsinki, Department of Chemistry, Organic laboratory, 1985

Unimolecular Gas Phase Reactions of Some Organophosphorus Ester Ions and Effects of Stepwise Collisional Excitation
Hilkka Kenttämaa
University of Helsinki, Department of Chemistry, Organic laboratory, 1985