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Kinetics of Free Radical Reactions

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Contact Information

Laboratory of Physical Chemistry
Department of Chemistry
A.I. Virtasen aukio 1
(P.O. BOX 55)
FI-00014 University of Helsinki
Finland

Group leader
Doc. Raimo Timonen, Ph.D.
Phone: +358-9-191 50302
email: raimo.timonen(at)helsinki.fi
Fax: +358-9-191 50279

Publications of the Group

Organised by year, most recent articles first.

  1. Matti P. Rissanen, Arkke J. Eskola, Elena Savina, Raimo S. Timonen:
    Kinetics of the Reactions of CH3CH2, CH3CHCl, and CH3CCl2 Radicals with NO2 in the Temperature Range 221-363 K.
    Journal of Physical Chemistry A (2009), 113(9), 1753-1759.

  2. Arkke J. Eskola, Iwona Golonka, Matti P. Rissanen and Raimo S. Timonen:
    Kinetics of the CCl2 + Br2 and CCl2 + NO2 reactions in the temperature range 266-365K and reactivity of the CCl2 biradical.
    Chemical Physics Letters  (2008),  460(4-6),  401-405.

  3. Arkke J. Eskola, Raimo S. Timonen, Paul Marshall, Evgeni N. Chesnokov and Lev N. Krasnoperov:
    Rate constants and hydrogen isotope substitution effects in the CH3 + HCl and CH3 + Cl2 reactions.
    The Journal of Physical Chemistry. A  (2008),  112(32),  7391-401.

  4. Arkke J. Eskola, Vladimir A. Lozovsky and Raimo S. Timonen:
    Kinetics of the reactions of C2H5, n-C3H7, and n-C4H9 radicals with Cl2 at the temperature range 190-360 K.
    International Journal of Chemical Kinetics  (2007),  39(11),  614-619.

  5. Arkke J. Eskola, Jorma A. Seetula and Raimo S. Timonen:
    Kinetics of the CH3 + HCl / DCl,  CH4 / CH3D + Cl and CD3 + HCl / DCl, CD3H / CD4 + Cl reactions: An experimental H atom tunneling investigation.
    Chemical Physics  (2006),  331(1),  26-34.

  6. Arkke J. Eskola, Dorota Wojcik-Pastuszka, Emil Ratajczak and Raimo S. Timonen:
    Kinetics of the Reactions of CH2I, CH2Br, and CHBrCl Radicals with NO2 in the Temperature Range 220-360 K.
    Journal of Physical Chemistry A  (2006),  110(44),  12177-12183.

  7. Arkke J. Eskola, Dorota Wojcik-Pastuszka, Emil Ratajczak and Raimo S. Timonen:
    Kinetics of the reactions of CH2Br and CH2I radicals with molecular oxygen at atmospheric temperatures.
    Physical Chemistry Chemical Physics  (2006),  8(12),  1416-1424.

  8. Arkke J. Eskola, Wolf D. Geppert, Matti P. Rissanen, Raimo S. Timonen and Lauri Halonen:
    Kinetics of the Reactions of Chlorinated Methyl Radicals (CH2Cl, CHCl2, and CCl3) with NO2 in the Temperature Range 220-360 K.
    Journal of Physical Chemistry A  (2005),  109(24),  5376-5381.

  9. Wolf D. Geppert, Arkke J. Eskola, Raimo S. Timonen and Lauri Halonen:
    Kinetics of the Reactions of Vinyl (C2H3) and Propargyl (C3H3) Radicals with NO2 in the Temperature Range 220-340 K.
    Journal of Physical Chemistry A  (2004),  108(19),  4232-4238.

  10. Arkke J. Eskola and Raimo S. Timonen:
    Kinetics of the reactions of vinyl radicals with molecular oxygen and chlorine at temperatures 200-362 K.
    Physical Chemistry Chemical Physics  (2003),  5(12),  2557-2561. 

  11. Matti P. Rissanen, Suula L. Arppe, Arkke J. Eskola, Matti M. Tammi and Raimo S. Timonen:
    Kinetics of the R + NO2 Reactions (R = i-C3H7, n-C3H7, s-C4H9, and t-C4H9) in the Temperature Range 201−489 K.
    Journal of Physical Chemistry A (2010) 114 (14), 4811–4817.

  12. Matti P. Rissanen, Arkke J. Eskola and Raimo S. Timonen:
    Kinetics of the Reactions of CH2Cl, CH3CHCl, and CH3CCl2 Radicals with Cl2 in the Temperature Range 191−363 K.
    Journal of Physical Chemistry A (2010), 114 (14), 4805–4810.